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Recent Advances in Science and Technology of Materials: Volume 3

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الناشر	Springer; Softcover Reprint of the Original 1st 1974 ed. edition
رقم الكتاب المعياري الدولي 10	1468472356
تنسيق الكتاب	Paperback
وصف الكتاب	If an ion in a crystal is replaced by an impurity ion with a different charge, compensation for the charge difference must be accomplished. This is usually done by an intrinsic defect, i. e. a lattice vacancy or interstitial host ion, in such a way to balance the excess or deficit of charge. The introduction of cation vacan cies along with divalent cation impurities in alkali halides is a familiar example. If these crystals are carefully annealed, nearly all of the compensating defects migrate to the impurity ions to form impurity-defect complexes. It is the behavior of these complexes that are the principal concern in this paper. Almost invariably such complexes are dipolar in character, and when subjected to an electric or mechanical stress field, they will tend to realign to an orienta tion of lower energy provided the thermal activation is sufficiently great. If the complex consists of an impurity-vacancy couple, re orientation may occur either by the vacancy moving around the impu rity or by an exchange of positions of the partners. In general the activation energy for these two distinct reorientation paths is different. If the complex consists of an impurity-interstitial couple, interchange of positions is unlikely and reorientation is considered to occur exclusively by the motion of the interstitial around the vacancy.
عدد الصفحات	408 pages

رقم الكتاب المعياري الدولي 13	9781468472356
الكاتب	Adlai Bishay
اللغة	English
تاريخ النشر	12 June 2012

مجموع السلة  273.00

Recent Advances in Science and Technology of Materials: Volume 3

273.00

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